supramolecular chemistry

Aromaticity and Antiaromaticity in the Excited States of Porphyrin Nanorings
Aromaticity can be a useful concept for predicting the behavior of excited states. Here we show that π-conjugated porphyrin nanorings …
April 2019 J. Phys. Chem. Lett.
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Aromaticity and Antiaromaticity in the Excited States of Porphyrin Nanorings
Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Doping, through oxidation or reduction, is often used to modify the properties of π-conjugated oligomers. In most cases, the resulting …
January 2019 Angewandte Chemie International Edition
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Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Template-Directed Synthesis of a Conjugated Zinc Porphyrin Nanoball
We report the template-directed synthesis of a π-conjugated 14-porphyrin nanoball. This structure consists of two intersecting …
April 2018 J. Am. Chem. Soc.
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Template-Directed Synthesis of a Conjugated Zinc Porphyrin Nanoball
Aromatic and antiaromatic ring currents in a molecular nanoring
Aromatic and antiaromatic molecules—which have delocalized circuits of [4n + 2] or [4n] electrons, respectively—exhibit ring currents …
January 2017 Nature
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Aromatic and antiaromatic ring currents in a molecular nanoring
Harnessing NMR relaxation interference effects to characterise supramolecular assemblies
Solution-state NMR spectroscopy remains the primary method for characterising synthetic supramolecular assemblies. Yet, in their NMR …
June 2016 Chem. Commun.
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Harnessing NMR relaxation interference effects to characterise supramolecular assemblies
Synthesis of Five-Porphyrin Nanorings by Using Ferrocene and Corannulene Templates
The smallest and most strained member of a family of π-conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl …
January 2016 Angewandte Chemie International Edition
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Synthesis of Five-Porphyrin Nanorings by Using Ferrocene and Corannulene Templates